Emission Tuning of Heteroleptic Arylborane-Ruthenium(II) Complexes by Ancillary Ligands: Observation of Strickler-Berg-Type Relation.
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DOI: 10.1021/acs.inorgchem.8b01058
Abstract: Novel heteroleptic arylborane-ruthenium(II) complexes having a series of ancillary ligands L' ([Ru(B2bpy)L'2]2+) in CH3CN showed low-energy/intense metal-to-ligand charge transfer (MLCT)-type absorption and intense/long-lived emission compared to the reference complexes. The spectroscopic and photophysical properties of… read more here.
Keywords: ruthenium complexes; ancillary ligands; type; arylborane ruthenium ... See more keywords