Mechanistic insights into silver(I)-mediated trifluoromethylation of aryldiazonium salts
Sign Up to like & getrecommendations! Published in 2019 at "Computational and Theoretical Chemistry"
DOI: 10.1016/j.comptc.2019.04.015
Abstract: Abstract The mechanism of silver(I)-mediated trifluoromethylation of aryldiazonium salts has been studied comprehensively with density functional theory (DFT). Three stages constitute the trifluoromethylation pathway, namely (i) dissociation of the aryldiazonium salt, (ii) formation of the… read more here.
Keywords: trifluoromethylation aryldiazonium; mediated trifluoromethylation; aryldiazonium; trifluoromethylation ... See more keywords
Two-Phase Electrochemical Generation of Aryldiazonium Salts: Application in Electrogenerated Copper-Catalyzed Sandmeyer Reactions.
Sign Up to like & getrecommendations! Published in 2020 at "Organic letters"
DOI: 10.1021/acs.orglett.0c02013
Abstract: The electrochemical generation of aryldiazonium salts from nitroarenes in a two-phase system (ethyl acetate/water) was reported for the first time. Some compounds including azo, azosulfone, and arylazides were prepared in good yields with good purity.… read more here.
Keywords: generation aryldiazonium; two phase; aryldiazonium salts; electrochemical generation ... See more keywords