Aryldimethylelement cations of the heavier group 14 elements. An essentially three-coordinate plumbylium ion.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d3cc00397c
Abstract: The kinetically stabilized group 14 cations [RindEMe2][B(C6F5)4] (E = Si, Sn, Pb) were prepared and fully characterized (Rind = dispiro[fluorene-9,3'-(1',1',7',7'-tetramethyl-s-hydrindacen-4'-yl)-5',9''-fluorene). The deshielded heteronuclear NMR chemical shifts (δ(29Si) = 160.4, δ(119Sn) = 619.9, δ(207Pb) = 1549.5)… read more here.
Keywords: heavier group; aryldimethylelement cations; group; elements essentially ... See more keywords