A visible light-mediated, decarboxylative, desulfonylative Smiles rearrangement for general arylethylamine syntheses.
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DOI: 10.1039/d0cc05049k
Abstract: A decarboxylative, desulfonylative Smiles rearrangement is presented that employs activated-ester/energy transfer catalysis to decarboxylate β-amino acid derived starting materials at room-temperature under visible light irradiation. The radical Smiles rearrangement gives a range of biologically active… read more here.
Keywords: arylethylamine; desulfonylative smiles; light mediated; visible light ... See more keywords