Iron(III) Arylhydrazone Complexes Immobilized on Amine-Functionalized Mesoporous Silica: Catalysts for the Valorization of Biomass-Derived Furfuryl Alcohol.
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DOI: 10.1002/cplu.202200363
Abstract: The aquasoluble FeIII complexes [Fe(H2 O)3 (L1 )] ⋅ 4H2 O (Fe1) and [Fe(H2 O)3 (L2 )] ⋅ 3H2 O (Fe2), bearing the basic forms of 5-chloro-3-(2-(4,4-dimethyl-2,6-dioxocyclohexylidene)hydrazinyl)-2-hydroxy-benzenesulfonic acid (H3 L1 ) and 3-(2-(2,4-dioxopentan-3-ylidene)hydrazinyl)-2-hydroxy-5-nitrobenzenesulfonic acid (H3 L2 ), were incorporated… read more here.
Keywords: furfuryl alcohol; arylhydrazone complexes; iron iii; amine functionalized ... See more keywords
Arylhydrazone Cd(II) and Cu(II) complexes as catalysts for secondary alcohol oxidation
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DOI: 10.1016/j.poly.2017.03.020
Abstract: Abstract Reaction of cadmium acetate hydrate with sodium 2-[2-(4,4-dimethyl-2,6-dioxocyclohexylidene)hydrazinyl]terephthalate (Na2HL), in the presence of imidazole (im), leads to the polymeric species [Cd(im)3(µ,η-HL-1κOO′:2κO″O‴)]n (1) that is characterized by IR spectroscopy, elemental analysis, UV–Vis absorption spectroscopy and… read more here.
Keywords: complexes catalysts; oxidation; catalysts secondary; arylhydrazone complexes ... See more keywords