Sonogashira Reaction Using Arylsulfonium Salts as Cross-Coupling Partners.
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DOI: 10.1021/acs.orglett.7b02764
Abstract: Triarylsulfonium, alkyl- and fluoroalkyl(diaryl)sulfonium, and aryl(dialkyl)sulfonium triflates are successfully used as a new family of cross-coupling participants in the Sonogashira reaction as aryldiazonium, diaryliodonium, and tetraphenylphosphonium salts. It was found that terminal alkynes reacted mildly… read more here.
Keywords: arylsulfonium salts; coupling partners; salts cross; sonogashira reaction ... See more keywords
Palladium-catalyzed phosphorylation of arylsulfonium salts with P(O)H compounds via C–S bond cleavage
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DOI: 10.1039/d2ra04297e
Abstract: Herein we report a novel palladium-catalyzed phosphorylation of arylsulfonium salts with P(O)H compounds via C–S bond cleavage under mild conditions. The protocol provides a pragmatic strategy applicable to the synthesis of diverse arylphosphonates. read more here.
Keywords: compounds via; catalyzed phosphorylation; phosphorylation arylsulfonium; palladium catalyzed ... See more keywords