Palladium-Catalyzed Dearomative Arylvinylation Reaction of Indoles with N-Arylsulfonylhydrazones
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DOI: 10.1021/acs.organomet.9b00112
Abstract: A Pd-catalyzed dearomative arylvinylation reaction of indoles with N-arylsulfonylhydrazones as coupling partners is developed, which proceeds via a domino sequence involving dearomative carbopalladation, Pd-carbene migratory insertion, and regioselective β-hydride elimination. A range of 3-vinylindolines bearing… read more here.
Keywords: arylvinylation; dearomative arylvinylation; arylvinylation reaction; catalyzed dearomative ... See more keywords