Radical Approach to the Chiral Quaternary Center in Asperaculin A: Synthesis of 9-Deoxyasperaculin A.
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DOI: 10.1021/acs.orglett.6b03854
Abstract: Diastereoselective approaches toward the synthesis of a marine-derived sesquiterpenoid fungal metabolite, asperaculin A, are delineated, combining step economy and simplicity. Two distinct lactonization sequences from a common intermediate led to the first synthesis of 9-deoxyasperaculin… read more here.
Keywords: asperaculin; approach chiral; synthesis deoxyasperaculin; radical approach ... See more keywords