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Published in 2018 at "Journal of Biological Inorganic Chemistry"
DOI: 10.1007/s00775-018-1575-3
Abstract: The Fe(II)/2-oxoglutarate-dependent dioxygenase AsqJ from Aspergillus nidulans catalyses two pivotal steps in the synthesis of quinolone antibiotic 4′-methoxyviridicatin, i.e., desaturation and epoxidation of a benzodiazepinedione. The previous experimental results signal that, during the desaturation reaction,…
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Keywords:
binding cavity;
desaturation reaction;
reaction;
dioxygenase ... See more keywords