Diamidophosphites from β-hydroxyamides: readily assembled ligands for Pd-catalyzed asymmetric allylic substitution.
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DOI: 10.1039/d0dt00741b
Abstract: Two groups of modular chiral diamidophosphite ligands were easily synthesised from accessible N-Boc-amino alcohols and pseudodipeptides. The reaction of these compounds with [Pd(allyl)Cl]2 in the presence of AgBF4 yielded complexes [Pd(allyl)(L)2]BF4. In addition, metallochelates [Pd(allyl)(L)]BF4… read more here.
Keywords: hydroxyamides readily; diamidophosphites hydroxyamides; assembled ligands; substitution ... See more keywords