Organoamine-Directed Assembly of 5p-4f Heterometallic Cluster Substituted Polyoxometalates: Luminescence and Proton Conduction Properties.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c02099
Abstract: The assembly of heterometallic cluster substituted polyoxometalates (POMs) remains a great challenge for inorganic synthetic chemistry up to now. Herein, a series of 5p-4f heterometallic cluster substituted POMs were successfully isolated by a facile one-step… read more here.
Keywords: heterometallic cluster; substituted polyoxometalates; chemistry; assembly heterometallic ... See more keywords
Phosphorus guiding palladium: [4 + 4] metallomacrocyclic PdII complex and self-assembly of heterometallic PdII/ZnII grid-type complex.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt01176j
Abstract: The reaction of heteroditopic ligand 1 featuring a hard pyridine-hydrazone-pyrimidine (N,N,N) site and a softer pyrimidine-hydrazone-phosphane (N,N,P) pocket with [Pd(CH3CN)4](OTf)2 in different metal-to-ligand ratios (M : L) gave the homobimetallic PdII complex [Pd2(1)(CH3CN)2](OTf)4 (2, M : L ratio 2 : 1),… read more here.
Keywords: assembly heterometallic; self assembly; pdii; heterometallic pdii ... See more keywords