Assembly of Uranyl Peroxides from Ball Milled Solids.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c01445
Abstract: Mechanochemistry enables transformations of highly insoluble materials such as uranium dioxide or the mineral studtite [(UO2)(O2)(H2O)2]ยท(H2O)2 into uranyl triperoxide compounds that can subsequently assemble into hydroxide-bridged uranyl peroxide dimers in the presence of lithium hydroxide.… read more here.
Keywords: assembly uranyl; uranyl peroxides; peroxides ball; milled solids ... See more keywords
Enhancing photosensitivity via the assembly of a uranyl coordination polymer.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc02985e
Abstract: Synergistic assembly of uranyl centres and luminescent 2,6-bis(pyrazol-1-yl)pyridine-4-carboxylates (bppCOOH) gives rise to a uranyl coordination polymer, namely U-bppCOO, which exhibits a luminescence quenching response toward UV or X-ray irradiation doses. Notably, the photosensitivity of U-bppCOO… read more here.
Keywords: uranyl coordination; assembly uranyl; coordination polymer;