Total Synthesis and Structure Assignment of Saptomycin H.
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DOI: 10.1021/acs.orglett.1c04306
Abstract: We report herein the first total synthesis of saptomycin H (2), by which the unidentified absolute stereochemistry of the oxiranyl side chain has been determined as 14R,16S. The keys include (1) concise assembly of three… read more here.
Keywords: assignment saptomycin; synthesis structure; synthesis; stereochemistry ... See more keywords