Microwave-assisted cleavage of cysteine perfluoroaryl thioethers
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DOI: 10.1007/s00726-020-02846-z
Abstract: The cysteine- perfluoroarene S N Ar reaction allows for the sequence-specific attachment of dyes and affinity tags to peptides and proteins. However, while many methods exist for the desulfuration of native and functionalized cysteine residues,… read more here.
Keywords: cysteine; microwave assisted; cleavage cysteine; cysteine perfluoroaryl ... See more keywords
Effect of Benzyl Functionality on Microwave-Assisted Cleavage of Cα–Cβ Bonds in Lignin Model Compounds
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DOI: 10.1021/acs.jpcc.6b12056
Abstract: The effect of benzylic alcohol (Cα—OH) pretreatments on microwave-assisted cleavage of Cα—Cβ bonds in lignin model compounds was investigated by combining experimental results with density functional theory (DFT) calculations at the M06-2X/6-311++G(d,p) level. The oxidization… read more here.
Keywords: cleavage; model compounds; microwave assisted; model ... See more keywords