Buffer Assists Electrocatalytic Nitrite Reduction by a Cobalt Macrocycle Complex.
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DOI: 10.1021/acs.inorgchem.2c00909
Abstract: This work reports a combined experimental and computational study of the activation of an otherwise catalytically inactive cobalt complex, [Co(TIM)Br2]+, for aqueous nitrite reduction. The presence of phosphate buffer leads to efficient electrocatalysis, with rapid… read more here.
Keywords: cobalt; nitrite reduction; buffer; reduction ... See more keywords