Ferrous complexes supported by sterically encumbered asymmetric bis(arylimino)acenaphthene (BIAN) ligands: synthesis, characterization and screening for catalytic hydrosilylation of carbonyl compounds
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DOI: 10.1039/c7ra01511a
Abstract: Six ferrous chloride complexes ((Ar-BIANX)FeCl2: Ar = 2,6-diisopropylphenyl (Dipp), X = F (1), Cl (2), Me (3); Ar = mesityl (Mes), X = F (4), Cl (5), Me (6)) supported by sterically bulky asymmetric bis(arylimino)acenaphthene… read more here.
Keywords: bian ligands; bis arylimino; arylimino acenaphthene; acenaphthene bian ... See more keywords
Crystal structure and DFT calculations of Cp2NbH(SiIMe2)(SiFMe2): an asymmetric bis(silyl) niobocene hydride complex.
Sign Up to like & getrecommendations! Published in 2023 at "Acta crystallographica. Section C, Structural chemistry"
DOI: 10.1107/s2053229623002395
Abstract: An asymmetric bis(silyl) niobocene hydride complex, namely, bis(η5-cyclopentadienyl)(fluorodimethylsilyl)hydrido(iododimethylsilyl)niobium, [Nb(C5H5)2(C2H6FSi)(C2H6ISi)H] or Cp2NbH(SiIMe2)(SiFMe2), has been studied to determine the effect of the silyl ligand on the position of the hydride attached to the Nb atom. It has… read more here.
Keywords: asymmetric bis; hydride; siime2 sifme2; cp2nbh siime2 ... See more keywords