Highly Enantioselective Construction of Dihydrooxazines via Pd-Catalyzed Asymmetric Carboetherification.
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DOI: 10.1021/acs.orglett.9b04123
Abstract: A straightforward synthesis of highly enantioenriched 5,6-dihydro-4H-1,2-oxazines is realized by Pd-catalyzed asymmetric carboetherification of γ,δ-alkenyl oximes with (hetero)aryl and alkenyl halides in the presence of a commercially available bisphosphine ligand. The enantioenriched products can be… read more here.
Keywords: catalyzed asymmetric; asymmetric carboetherification; enantioselective construction; highly enantioselective ... See more keywords