Efficient and Spatially Controlled Functionalization of SBA‐15 and Initial Results in Asymmetric Rh‐Catalyzed 1,2‐Additions under Confinement
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DOI: 10.1002/cctc.202100229
Abstract: Selectively functionalized mesoporous silica may considerably advance heterogeneous catalysis through the controlled immobilization of highly selective complex catalysts inside the mesopores. However, spatially controlled functionalization and the precise analytical verification are still a challenge. In… read more here.
Keywords: controlled functionalization; efficient spatially; sba; spatially controlled ... See more keywords
Asymmetric Ni-catalyzed Radical Relayed Reductive Coupling.
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DOI: 10.1021/jacs.0c05254
Abstract: Alkene dicarbofunctionalizations represent streamline the construction of aliphatic structures and have thus been the subject of intense research efforts. Despite significant progress, catalytic asymmetric variants remain scarce. Inspired by the advantages of reductive cross-coupling approaches,… read more here.
Keywords: methodology; radical relayed; catalyzed radical; asymmetric catalyzed ... See more keywords