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Published in 2019 at "Organic letters"
DOI: 10.1021/acs.orglett.9b00479
Abstract: A unified strategy for the construction of prevalent 1,3,5,... n (OH, Me) motifs based on consecutive copper-catalyzed asymmetric conjugate borylation (ACB) and methylation (ACA) reactions involving α,β-unsaturated 2-acyl- N-methylimidazoles is described. Good yields and high…
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Keywords:
catalyzed asymmetric;
asymmetric conjugate;
unified strategy;
copper catalyzed ... See more keywords
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Published in 2019 at "Organic letters"
DOI: 10.1021/acs.orglett.9b01637
Abstract: ( S)-2,15-Br2-DHTP-catalyzed asymmetric conjugate addition of boronic acids to β-trifluoromethyl α,β-unsaturated ketones and enones was studied. The reaction afforded the corresponding Michael addition products in moderate to high yields with excellent enantioselectivities (up to 99:1…
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Keywords:
catalyzed asymmetric;
boronic acids;
addition;
conjugate addition ... See more keywords
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Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc00146b
Abstract: A Cu-catalyzed asymmetric 1,6-conjugate addition of in situ generated para-quinone methides (p-QMs) with β-ketoester has been developed to construct a ketoester skeleton bearing an adjacent tertiary-quaternary carbon stereocenter in good yields and high enantioselectivities. This…
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Keywords:
situ generated;
asymmetric conjugate;
addition situ;
conjugate addition ... See more keywords