Asymmetric Cyanosilylation of Aldehydes by a Lewis Acid/Base Synergistic Catalyst of Chiral Metal Clusters.
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DOI: 10.1021/acs.inorgchem.1c03916
Abstract: Metal clusters with well-defined crystal structures are extremely useful for studying the synergistic catalytic effects and associated catalytic mechanisms. In this study, two pairs of chiral lanthanide-transition metal clusters (R)/(S)-Co3Ln2 (Ln = Tb or Dy)… read more here.
Keywords: metal clusters; asymmetric cyanosilylation; lewis acid; metal ... See more keywords