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Published in 2020 at "Organic letters"
DOI: 10.1021/acs.orglett.0c02026
Abstract: Asymmetric dearomatizing fluorocyclization of indole derivatives was investigated using a dicarboxylate phase-transfer catalyst. This reaction proceeds under mild reaction conditions to provide fluoropyrroloindoline derivatives in a highly enantioselective manner. Various substitution patterns on the indole…
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Keywords:
phase transfer;
indole derivatives;
transfer catalyst;
asymmetric dearomatizing ... See more keywords
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Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c01106
Abstract: Nonactivated arenes, such as benzene derivatives, are chemically inert due to their intrinsic aromaticity and low polarity. The catalytic asymmetric dearomatization (CADA, coined by You and co-workers) of the nonactivated arenes represents a formidable challenge.…
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Keywords:
organocatalytic asymmetric;
asymmetric dearomatizing;
reaction;
hetero diels ... See more keywords