Articles with "asymmetric dehydrogenative" as a keyword



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Asymmetric C-H Dehydrogenative Allylic Alkylation by Ternary Photoredox-Cobalt-Chiral Primary Amine Catalysis under Visible Light.

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Published in 2022 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.2c03299

Abstract: We report herein an asymmetric C-H dehydrogenative allylic alkylation by a synergistic catalytic system involving a chiral primary amine, a photoredox catalyst, and a cobaloxime cocatalyst. The ternary catalytic system enables the coupling of β-ketocarbonyls… read more here.

Keywords: primary amine; allylic alkylation; chiral primary; dehydrogenative allylic ... See more keywords