Catalytic asymmetric C–H insertion reactions of vinyl carbocations
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DOI: 10.1126/science.ade5320
Abstract: From the preparation of pharmaceuticals to enzymatic construction of natural products, carbocations are central to molecular synthesis. Although these reactive intermediates are engaged in stereoselective processes in nature, exerting enantiocontrol over carbocations with synthetic catalysts… read more here.
Keywords: vinyl cation; asymmetric insertion; vinyl carbocations; insertion ... See more keywords