Two zinc(II) coordination complexes based on an asymmetric multidentate ligand: syntheses, structures, selective fluorescence sensing of iron(III) ions and thermal analyses.
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DOI: 10.1107/s205322961701717x
Abstract: The rational selection of ligands is vitally important in the construction of coordination complexes. Two novel ZnII complexes, namely bis(acetato-κO)bis[1-(1H-benzotriazol-1-ylmethyl)-2-propyl-1H-imidazole-κN3]zinc(II) monohydrate, [Zn(C13H15N5)2(C2H3O2)2]·H2O, (1), and bis(azido-κN1)bis[1-(1H-benzotriazol-1-ylmethyl)-2-propyl-1H-imidazole-κN3]zinc(II), [Zn(C13H15N5)2(N3)2], (2), constructed from the asymmetric multidentate imidazole ligand, have… read more here.
Keywords: fluorescence; zinc; coordination complexes; asymmetric multidentate ... See more keywords