Factors driving the Ni/Cu cooperative asymmetric propargylation of aldimine esters.
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DOI: 10.1039/d3cc01309j
Abstract: The factors driving the Ni0(binap)/CuI(phospherrox) cooperative asymmetric propargylation of aldimine esters are unveiled through DFT calculations. The system is fully explored accounting for conformational complexity and aggregation steps. The activation of the substrates proceeds independently,… read more here.
Keywords: aldimine esters; factors driving; cooperative asymmetric; asymmetric propargylation ... See more keywords