Catalytic Asymmetric Radical Diamination of Alkenes
Sign Up to like & getrecommendations! Published in 2017 at "Chem"
DOI: 10.1016/j.chempr.2017.10.008
Abstract: Summary Catalytic asymmetric diamination of alkenes is a highly attractive method for creating chiral vicinal diamines, which are ubiquitous in biologically active molecules and versatile ligands as well as organocatalysts. We report the use of… read more here.
Keywords: diamination; asymmetric radical; diamination alkenes; reaction ... See more keywords
Asymmetric Radical Bicyclization for Stereoselective Construction of Tricyclic Chromanones and Chromanes with Fused Cyclopropanes.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.3c01618
Abstract: Asymmetric radical bicyclization processes have been developed via metalloradical catalysis (MRC) to stereoselectively construct chiral chromanones and chromanes bearing fused cyclopropanes. Through optimization of a versatile D2-symmetric chiral amidoporphyrin ligand platform, a Co(II)-metalloradical system can… read more here.
Keywords: radical bicyclization; bicyclization; chromanones chromanes; asymmetric radical ... See more keywords
Photoinduced copper-catalyzed asymmetric radical three-component cross-coupling of 1,3-enynes with oxime esters and carboxylic acids
Sign Up to like & getrecommendations! Published in 2023 at "Organic Chemistry Frontiers"
DOI: 10.1039/d3qo00513e
Abstract: Catalytic radical difunctionalization of 1,3-enynes has recently been established as a potentially robust platform for construction of valuable allenes and propargylic compounds. Despite considerable advances made in the realm of... read more here.
Keywords: radical three; asymmetric radical; catalyzed asymmetric; three component ... See more keywords