Biocatalytical Asymmetric Sulfoxidation by Identifying Cytochrome P450 from Parvibaculum Lavamentivorans DS‐1
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DOI: 10.1002/cctc.201801139
Abstract: Cytochrome P450 monooxygenases (P450s) catalyzed asymmetric sulfoxidation represents a green route for the synthesis of valuable enantiopure sulfoxides, which are potentially interesting synthons in synthetic and pharmaceutical chemistry. Here the potential P450 and redox partner… read more here.
Keywords: parvibaculum lavamentivorans; biocatalytical asymmetric; asymmetric sulfoxidation; p450 ... See more keywords
An efficient silica supported Chitosan@vanadium catalyst for asymmetric sulfoxidation and its application in the synthesis of esomeprazole
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DOI: 10.1016/j.catcom.2017.01.018
Abstract: Abstract A new type of silica supported Chitosan@vanadium complex was used as a highly active heterogeneous catalyst for asymmetric oxidation of aryl alkyl sulfides. With the economic aqueous H2O2 (30%) as the oxidant, the oxidation… read more here.
Keywords: catalyst asymmetric; silica supported; asymmetric sulfoxidation; chitosan vanadium ... See more keywords
Ultraviolet-responsive self-assembled metallomicelles for photocontrollable catalysis of asymmetric sulfoxidation in water
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DOI: 10.1039/c7ra11022g
Abstract: Self-assembled metallomicelles with ultraviolet (UV)-controlled morphologies were constructed from a synthesized azobenzene-containing amphiphilic chiral salen TiIV catalyst. The morphologies of the metallomicelles could be well adjusted by changing the UV irradiation time, and this was… read more here.
Keywords: assembled metallomicelles; asymmetric sulfoxidation; catalysis; self assembled ... See more keywords