Asymmetrically Coordinated Heterodimetallic Ir-Ru System: Synthesis, Computational, and Anticancer Aspects.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.3c00272
Abstract: Herein, we present an unprecedented formation of a heterodinuclear complex [{(ppy)2IrIII}(μ-phpy){RuII(tpy)}](ClO4)2 {[1](ClO4)2} using terpyridyl/phenylpyridine as ancillary ligands and asymmetric phpy as a bridging ligand. The asymmetric binding mode (N∧N-∩-N∧N∧C-) of the phpy ligand in {[1](ClO4)2}… read more here.
Keywords: coordinated heterodimetallic; clo4; asymmetrically coordinated; ligand ... See more keywords
An asymmetrically coordinated Zn-Co diatomic site catalyst for efficient hydrogen evolution reactions.
Sign Up to like & getrecommendations! Published in 2024 at "Chemical communications"
DOI: 10.1039/d4cc01832j
Abstract: We propose an innovative preparation method, namely, a two-step pyrolysis process, to synthesize Zn-Co bimetallic catalysts with excellent hydrogen evolution performance. In the synthesized Zn1Co1-SNC catalyst, there exists a strong interaction between Zn and Co,… read more here.
Keywords: catalyst; hydrogen evolution; asymmetrically coordinated; coordinated diatomic ... See more keywords