Homoleptic Perchlorophenyl "Ate" Complexes of Thorium(IV) and Uranium(IV).
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c01686
Abstract: The reaction of AnCl4(DME)n (An = Th, n = 2; U, n = 0) with 5 equiv of LiC6Cl5 in Et2O resulted in the formation of homoleptic actinide-aryl "ate" complexes [Li(DME)2(Et2O)]2[Li(DME)2][Th(C6Cl5)5]3 ([Li][1]) and [Li(Et2O)4][U(C6Cl5)5] ([Li][2]).… read more here.
Keywords: et2o; ate complexes; homoleptic perchlorophenyl; complexes thorium ... See more keywords
Early Lanthanide(III) Ate Complexes Featuring Ln-Si Bonds (Ln = La, Ce): Synthesis, Structural Characterization, and Bonding Analysis.
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DOI: 10.1021/acs.inorgchem.2c01830
Abstract: While research on lanthanide (Ln) complexes with silyl ligands is receiving growing attention, significantly unbalanced efforts have been devoted to different Ln elements. In comparison with the intense investigations on Ln elements such as Sm… read more here.
Keywords: early lanthanide; silyl lanthanum; chemistry; ate complexes ... See more keywords