Metal atom chemistry as a direct pathway to access homoleptic mono- and dinuclear isonitrile compounds of the iron triad Fe, Co, and Ni.
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DOI: 10.1039/d5dt01275a
Abstract: The co-condensation of atomic metal vapors of iron, nickel and cobalt with toluene, followed by a direct reaction with isonitriles, between -30 °C and -78 °C, yields stable homoleptic metal isonitrile complexes. Complexes of Fe,… read more here.
Keywords: chemistry; chemistry direct; metal atom; atom chemistry ... See more keywords