Halogen-atom and group transfer reactivity enabled by hydrogen tunneling
Sign Up to like & getrecommendations! Published in 2022 at "Science"
DOI: 10.1126/science.abq8663
Abstract: The generation of carbon radicals by halogen-atom and group transfer reactions is generally achieved using tin and silicon reagents that maximize the interplay of enthalpic (thermodynamic) and polar (kinetic) effects. In this work, we demonstrate… read more here.
Keywords: halogen atom; carbon; atom group; atom ... See more keywords