Cobalt-Catalyzed Nitrogen Atom Insertion in Arylcycloalkenes.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c10570
Abstract: Developing strategies enabling the modification of underlying molecular frameworks facilitates access to underexplored chemical spaces. Skeletal editing is an emerging technology for late-stage diversification of bioactive molecules. However, the current state of this knowledge remains… read more here.
Keywords: cobalt catalyzed; methodology; insertion arylcycloalkenes; catalyzed nitrogen ... See more keywords
A Thorium Chalcogenolate Series Generated by Atom Insertion into Thorium-Carbon Bonds.
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DOI: 10.1021/jacs.7b02356
Abstract: A new thorium monoalkyl complex, Th(CH2SiMe3)(L3) (L = MeC(NiPr)2) (2), undergoes insertion of chalcogen atoms resulting in a series of thorium chalcogenolate complexes, Th(ECH2SiMe3)(L3) (E = S, SS, Se, Te; 5-8). Complex 6 represents the… read more here.
Keywords: thorium chalcogenolate; insertion; thorium; atom insertion ... See more keywords
Nitrogen atom insertion into indenes to access isoquinolines
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DOI: 10.1039/d2sc06952k
Abstract: We report a convenient protocol for a nitrogen atom insertion into indenes to afford isoquinolines. The reaction uses a combination of commercially available phenyliodine(iii) diacetate (PIDA) and ammonium carbamate as the nitrogen source to furnish… read more here.
Keywords: access isoquinolines; indenes access; nitrogen atom; atom insertion ... See more keywords