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   Articles with "atom insertion" as a keyword



Asymmetric Multi-Atom Insertion of Esters via Rh-Catalyzed Ring Opening of Oxabicyclic Alkenes.

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recommendations! Published in 2025 at "Organic letters"

DOI: 10.1021/acs.orglett.5c00971

Abstract: Precise skeletal manipulation involving insertion, deletion, and replacement has garnered considerable attention within the synthetic chemistry community. Among these processes, multi-atom insertion reactions in acyclic compounds remain a formidable challenge, primarily due to the low… read more here.

Keywords: multi atom; via catalyzed; asymmetric multi; insertion ... See more keywords

Cobalt-Catalyzed Nitrogen Atom Insertion in Arylcycloalkenes.

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recommendations! Published in 2022 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.2c10570

Abstract: Developing strategies enabling the modification of underlying molecular frameworks facilitates access to underexplored chemical spaces. Skeletal editing is an emerging technology for late-stage diversification of bioactive molecules. However, the current state of this knowledge remains… read more here.

Keywords: cobalt catalyzed; methodology; insertion arylcycloalkenes; catalyzed nitrogen ... See more keywords

A Thorium Chalcogenolate Series Generated by Atom Insertion into Thorium-Carbon Bonds.

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recommendations! Published in 2017 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.7b02356

Abstract: A new thorium monoalkyl complex, Th(CH2SiMe3)(L3) (L = MeC(NiPr)2) (2), undergoes insertion of chalcogen atoms resulting in a series of thorium chalcogenolate complexes, Th(ECH2SiMe3)(L3) (E = S, SS, Se, Te; 5-8). Complex 6 represents the… read more here.

Keywords: thorium chalcogenolate; insertion; thorium; atom insertion ... See more keywords

Direct oxygen insertion into C-C bond of styrenes with air

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recommendations! Published in 2024 at "Nature Communications"

DOI: 10.1038/s41467-024-53266-6

Abstract: Skeletal editing of single-atom insertion to basic chemicals has been demonstrated as an efficient strategy for the discovery of structurally diversified compounds. Previous endeavors in skeletal editing have successfully facilitated the insertion of boron, nitrogen,… read more here.

Keywords: reaction; oxygen; insertion; oxygen insertion ... See more keywords

Nitrogen atom insertion into indenes to access isoquinolines

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recommendations! Published in 2023 at "Chemical Science"

DOI: 10.1039/d2sc06952k

Abstract: We report a convenient protocol for a nitrogen atom insertion into indenes to afford isoquinolines. The reaction uses a combination of commercially available phenyliodine(iii) diacetate (PIDA) and ammonium carbamate as the nitrogen source to furnish… read more here.

Keywords: access isoquinolines; indenes access; nitrogen atom; atom insertion ... See more keywords