Atom‐Precise Heteroatom Core‐Tailoring of Nanoclusters for Enhanced Solar Hydrogen Generation
Sign Up to like & getrecommendations! Published in 2023 at "Advanced Materials"
DOI: 10.1002/adma.202207765
Abstract: While core–shell nanomaterials are highly desirable for realizing enhanced optical and catalytic properties, their synthesis with atomic‐level control is challenging. Here, the synthesis and crystal structure of [Au12Ag32(SePh)30]4−, the first example of selenolated Au–Ag core–shell… read more here.
Keywords: atom precise; core; structure; precise heteroatom ... See more keywords
Atom-Precise Chiral Lanthanide-Silver(I) Heterometallic Clusters Ln3Ag5.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c02991
Abstract: Three pairs of chiral Ln-Ag(I) clusters d/l-Ln3Ag5 with C3 symmetry were prepared by d/l-penicillamine as multidentate ligand bridged Ln3+ and Ag(I) ions. The chiral ligand induced the molecular cluster to be chiral, and the CD… read more here.
Keywords: atom precise; silver heterometallic; precise chiral; chiral lanthanide ... See more keywords