Visible‐Light‐Mediated Dehydrogenative Cross‐Coupling: Synthesis of Nonsymmetrical Atropisomeric Biaryls
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DOI: 10.1002/ajoc.201700242
Abstract: The direct cross dehydrogenative coupling (CDC) reactions of unfunctionalized 2-naphthylamine/2-naphthol analogues with various aniline/phenol derivatives for the preparation of nonsymmetrical atropisomeric biaryl compounds, especially the BINOL-type biaryls, were disclosed using photocatalyst under the irradiation of… read more here.
Keywords: biaryls; chemistry; nonsymmetrical atropisomeric; visible light ... See more keywords
Catalytic enantioselective synthesis of atropisomeric biaryls by a cation-directed O-alkylation
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DOI: 10.1038/nchem.2710
Abstract: Axially chiral biaryls, as exemplified by 1,1′-bi-2-naphthol (BINOL), are key components of catalysts, natural products and medicines. These materials are synthesized conventionally in enantioenriched form through metal-mediated cross coupling, de novo construction of an aromatic… read more here.
Keywords: biaryls; synthesis atropisomeric; biaryls cation; alkylation ... See more keywords