Porous Supramolecular Assembly of Pentiptycene-Containing Gold(I) Complexes: Persistent Excited-State Aurophilicity and Inclusion-Induced Emission Enhancement.
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DOI: 10.1021/acs.inorgchem.2c01786
Abstract: We report herein a porous supramolecular framework formed by a linear mononuclear Au(I) complex (1) via the tongue-and-groove-like joinery between the pentiptycene U-cavities (grooves) and the rod-shaped π-conjugated backbone and alkyl chains (tongues) with the… read more here.
Keywords: porous supramolecular; inclusion induced; aurophilicity; excited state ... See more keywords