Hidden Complexity in the Mechanism of the Autoreduction of Myoglobin Compound II
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DOI: 10.1021/acsomega.2c02798
Abstract: The non-native oxidation of horse heart myoglobin with hydrogen peroxide produces compound II which autoreduces by utilizing an internal oxidation site. Here, we utilize full UV–visible time-dependent kinetics with global kinetic singular value decomposition analysis… read more here.
Keywords: hydrogen peroxide; myoglobin compound; compound; myoglobin ... See more keywords
Revisiting copper reduction in zeolites: the impact of autoreduction and sample synthesis procedure.
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DOI: 10.1039/c8cc03921f
Abstract: At least two distinct processes occur during heating of the copper-exchanged mordenite in oxygen-free environment depending on the sample synthesis procedure. The first process corresponds to the reaction of Cu(ii) sites with the residual traces… read more here.
Keywords: sample synthesis; synthesis procedure; copper; autoreduction ... See more keywords