In(OTf)3-Only-Catalyzed Glycosylation via Activation of an Alkyne Appended with an Amide Auxiliary Group.
Sign Up to like & getrecommendations! Published in 2025 at "Organic letters"
DOI: 10.1021/acs.orglett.5c00219
Abstract: We herein present the development of a novel glycosylation protocol using glycosyl o-N-(o-methoxybenzamidoyl)-propynyl benzoates as donors, activated solely by a catalytic amount of In(OTf)3, eliminating the need for a Au(I) catalyst. This approach offers mild… read more here.
Keywords: glycosylation; catalyzed glycosylation; auxiliary group; glycosylation via ... See more keywords