Excitation-Wavelength-Dependent and Auxiliary-Ligand-Tuned Intersystem-Crossing Efficiency in Cyclometalated Platinum(II) Complexes: Spectroscopic and Theoretical Studies.
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DOI: 10.1021/acs.inorgchem.0c01192
Abstract: Understanding the factors affecting the intersystem-crossing (ISC) rate constant (kISC) of transition-metal complexes is crucial to material design with tailored photophysical properties. Most of the works on ISC to date focused on the influence by… read more here.
Keywords: state; auxiliary ligand; intersystem crossing; efficiency ... See more keywords
Role of the Auxiliary Ligand in the Spontaneous Resolution of Enantiomers in Three-Dimensional Coordination Polymers.
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DOI: 10.1021/acs.inorgchem.1c00608
Abstract: Four pairs of chiral 3D coordination polymers (CPs), [Zn2(BDC)(lac)(DMF)]·guest (2) (H2BDC = benzene dicarboxylic acid; H2lac = lactic acid; guest = 1.5DMF + i-PrOH), [Co2(BDC)(lac)(DMF)]·guest (3) (guest = DMF + 2H2O), [Fe4(BDC)3(lac)2(DMF)2](CO3)·guest (4) (guest =… read more here.
Keywords: auxiliary ligand; coordination; dmf; resolution enantiomers ... See more keywords
Organic Azide and Auxiliary-Ligand-Free Complexes of Coinage Metals Supported by N-Heterocyclic Carbenes.
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DOI: 10.1021/acs.inorgchem.9b02771
Abstract: Organic azide complexes of copper(I) and silver(I), [(SIPr)CuN(1-Ad)NN][SbF6], [(SIPr)CuN(2-Ad)NN][SbF6], [(SIPr)CuN(Cy)NN][SbF6], and [(SIPr)AgN(1-Ad)NN][SbF6] have been synthesized by using Ag[SbF6] and the corresponding organic azides with (SIPr)CuBr and (SIPr)AgCl (SIPr = 1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene). The copper and silver organic… read more here.
Keywords: auxiliary ligand; ligand free; organic azide; sbf6 ... See more keywords