Theoretical investigation of the effect of auxiliary ligands on dipyrazole-bridged binuclear Cu(II) complexes
Sign Up to like & getrecommendations! Published in 2021 at "Chemical Physics Letters"
DOI: 10.1016/j.cplett.2021.139102
Abstract: Abstract The anti-configuration of a 3,5-bis(2-pyridyl)dipyrazolate-bridged binuclear Cu(II) complex (anti-Cu2(bpypz)2(DCNE)2) and its magnetostructural correlations were studied at the B1LYP/def2-TZVPP level of theory. The calculated magnetic coupling constant was consistent with the experimental value. Molecular magnetic… read more here.
Keywords: effect auxiliary; bridged binuclear; ligands dipyrazole; auxiliary ligands ... See more keywords
New ruthenium compounds bearing semicarbazone 2-formylopyridine moiety: Playing with auxiliary ligands for tuning the mechanism of biological activity.
Sign Up to like & getrecommendations! Published in 2017 at "Journal of inorganic biochemistry"
DOI: 10.1016/j.jinorgbio.2017.07.006
Abstract: Two ruthenium(II) complexes Ru1 and Ru2 bearing as a one ligand 2,2'-bipyridine substituted by a semicarbazone 2-formylopyridine moiety (bpySC: 5-(4-{4'-methyl-[2,2'-bipyridine]-4-yl}but-1-yn-1-yl)pyridine-2-carbaldehyde semicarbazone) and as the others 2,2'-bipyridine (bpy) and 4,7-diphenyl-1,10-phenanthroline (dip), respectively, as auxiliary ligands have… read more here.
Keywords: biological activity; semicarbazone formylopyridine; ligands tuning; auxiliary ligands ... See more keywords
Decamethyltitanocene hydride intermediates in the hydrogenation of the corresponding titanocene-(η2-ethene) or (η2-alkyne) complexes and the effects of bulkier auxiliary ligands.
Sign Up to like & getrecommendations! Published in 2017 at "Dalton transactions"
DOI: 10.1039/c7dt01545c
Abstract: 1H NMR studies of reactions of titanocene [Cp*2Ti] (Cp* = η5-C5Me5) and its derivatives [Cp*(η5:η1-C5Me4CH2)TiMe] and [Cp*2Ti(η2-CH2[double bond, length as m-dash]CH2)] with excess dihydrogen at room temperature and pressures lower than 1 bar revealed the… read more here.
Keywords: bulkier auxiliary; hydrogenation; auxiliary ligands; alkyne complexes ... See more keywords