Preparation of enantioenriched helical- and axial-chiral molecules by dynamic asymmetric induction.
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DOI: 10.1039/d1cc05881a
Abstract: Dynamic asymmetric induction (DYASIN) of racemic dynamic chiral heterohelicenes afforded their highly enantioenriched forms (up to 96% ep) in quantitative yields. These heterohelicenes were readily converted into semi-static axial-chiral 1,1'-binaphthyl derivatives in a stereospecific manner. read more here.
Keywords: enantioenriched helical; preparation enantioenriched; dynamic asymmetric; asymmetric induction ... See more keywords