Effective tuning of magnetic anisotropy in distorted pentagonal bipyramidal Ni(II) complexes via substitution of axial coligands.
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DOI: 10.1039/d2dt02867k
Abstract: A series of Ni(II) complexes with pyridine-based macrocyclic ligand L (3,12,18-triaza-6,9-dioxabicyclo[12.3.1]octadeca-1(18),14,16-triene) with general formula [Ni(L)(X)2]0/2+ (X = Br- (1), I- (2), CH3CN (3), NCS- (4), imidazole (5)) was prepared and thoroughly investigated. X-ray molecular structures… read more here.
Keywords: magnetic anisotropy; pentagonal bipyramidal; bipyramidal complexes; axial coligands ... See more keywords