Introducing two-dimensional metal-organic frameworks with axial coordination anion into Pebax for CO2/CH4 separation
Sign Up to like & getrecommendations! Published in 2020 at "Separation and Purification Technology"
DOI: 10.1016/j.seppur.2020.118107
Abstract: Abstract Two-dimensional (2D) MOF named Cu(BPY)2(OTF)2 (OTF = trifluoromethanesulfonic acid anion (CF3SO3−), BPY = 4,4-bipyridine) possessing axial coordination anion was prepared, and then combined into Pebax® MH 1657 (Pebax) polymer to fabricate mixed matrix membranes (MMMs) for the separation… read more here.
Keywords: anion; pebax; bpy otf; coordination anion ... See more keywords
Hofmann Metal-Organic Framework Monolayer Nanosheets as an Axial Coordination Platform for Biosensing.
Sign Up to like & getrecommendations! Published in 2019 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.9b00693
Abstract: Two-dimensional (2D) nanomaterials are remarkably attractive platform candidates for signal transduction through fluorescence resonance energy transfer or photo-induced electron-transfer pathway. In this work, a 2D Hofmann metal organic framework (hMOF) monolayer nanosheet was developed as… read more here.
Keywords: axial coordination; platform; coordination platform; monolayer nanosheets ... See more keywords
Effect of an axial coordination environment on quantum tunnelling of magnetization for dysprosium single-ion magnets with theoretical insight.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d1dt03678e
Abstract: Herein, we report two mononuclear dysprosium complexes [Dy(H4L){B(OMe)2(Ph)2}2](Cl)·MeOH (1) and [Dy(H4L){MeOH)2(NCS)2}](Cl) (2) [where H4L = 2,2'-(pyridine-2,6-diylbis(ethan-1-yl-1-ylidene))bis(N-phenylhydrazinecarboxamide)] with different axial coordination environments. The structural analysis revealed that the pentadentate H4L ligand binds through the equatorial position… read more here.
Keywords: ion magnets; dysprosium; axial coordination; meoh ... See more keywords