Axial Coordination Regulating Electronic Delocalization of p‐Block In−N4 Sites to Accelerate Sulfur Reduction Reaction
Sign Up to like & getrecommendations! Published in 2025 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202505204
Abstract: Modulating the electron delocalization of catalysts can improve the activation and conversion capabilities of lithium polysulfides (LiPSs) in lithium‐sulfur batteries, while the precise mechanism underlying this enhancement remains unclear. Herein, a p‐block In single‐atom catalysts… read more here.
Keywords: axial coordination; sulfur reduction; accelerate sulfur; block ... See more keywords
Manipulating Spin States by Metal Axial Coordination of Active Sites for Generating Valuable CH4 in CO2 Reduction.
Sign Up to like & getrecommendations! Published in 2025 at "Advanced science"
DOI: 10.1002/advs.202517166
Abstract: Dual‐atom catalysts (DACs) exhibit superior catalytic performance with more active sites and diverse electronic structures. However, electronic spin state as the crucial factor is rarely explicitly studied, and the in‐depth understanding of the electronic structures… read more here.
Keywords: axial coordination; co2 reduction; active sites; spin ... See more keywords
Unraveling the Fundamentals of Axial Coordination FeN4+1 Sites Regulating the Peroxymonosulfate Activation for Fenton-Like Activity.
Sign Up to like & getrecommendations! Published in 2024 at "Small"
DOI: 10.1002/smll.202405012
Abstract: Precise modulation of the axial coordination microenvironment in single-atom catalysts (SACs) to enhance peroxymonosulfate (PMS) activation represents a promising yet underexplored approach. This study introduces a pyrolysis-free strategy to fabricate SACs with well-defined axial-FeN4+1 coordination… read more here.
Keywords: fen4; axial coordination; pms activation; activation ... See more keywords
Introducing two-dimensional metal-organic frameworks with axial coordination anion into Pebax for CO2/CH4 separation
Sign Up to like & getrecommendations! Published in 2020 at "Separation and Purification Technology"
DOI: 10.1016/j.seppur.2020.118107
Abstract: Abstract Two-dimensional (2D) MOF named Cu(BPY)2(OTF)2 (OTF = trifluoromethanesulfonic acid anion (CF3SO3−), BPY = 4,4-bipyridine) possessing axial coordination anion was prepared, and then combined into Pebax® MH 1657 (Pebax) polymer to fabricate mixed matrix membranes (MMMs) for the separation… read more here.
Keywords: anion; pebax; bpy otf; coordination anion ... See more keywords
Hofmann Metal-Organic Framework Monolayer Nanosheets as an Axial Coordination Platform for Biosensing.
Sign Up to like & getrecommendations! Published in 2019 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.9b00693
Abstract: Two-dimensional (2D) nanomaterials are remarkably attractive platform candidates for signal transduction through fluorescence resonance energy transfer or photo-induced electron-transfer pathway. In this work, a 2D Hofmann metal organic framework (hMOF) monolayer nanosheet was developed as… read more here.
Keywords: axial coordination; platform; coordination platform; monolayer nanosheets ... See more keywords
Effect of an axial coordination environment on quantum tunnelling of magnetization for dysprosium single-ion magnets with theoretical insight.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d1dt03678e
Abstract: Herein, we report two mononuclear dysprosium complexes [Dy(H4L){B(OMe)2(Ph)2}2](Cl)·MeOH (1) and [Dy(H4L){MeOH)2(NCS)2}](Cl) (2) [where H4L = 2,2'-(pyridine-2,6-diylbis(ethan-1-yl-1-ylidene))bis(N-phenylhydrazinecarboxamide)] with different axial coordination environments. The structural analysis revealed that the pentadentate H4L ligand binds through the equatorial position… read more here.
Keywords: ion magnets; dysprosium; axial coordination; meoh ... See more keywords