Selective Axial-to-Equatorial Epimerization of Carbohydrates.
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DOI: 10.1021/jacs.2c04743
Abstract: Radical-mediated transformations have emerged as powerful methods for the synthesis of rare and unnatural branched, deoxygenated, and isomeric sugars. Here, we describe a radical-mediated axial-to-equatorial alcohol epimerization method to transform abundant glycans into rare isomers.… read more here.
Keywords: axial equatorial; epimerization; selective axial; epimerization carbohydrates ... See more keywords