Acceptor Copolymerized Axially Chiral Conjugated Polymers with TADF Properties for Efficient Circularly Polarized Electroluminescence
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DOI: 10.1002/advs.202309031
Abstract: Chiral conjugated polymer has promoted the development of the efficient circularly polarized electroluminescence (CPEL) device, nevertheless, it remains a challenge to develop chiral polymers with high electroluminescence performance. Herein, by the acceptor copolymerization of axially… read more here.
Keywords: chiral conjugated; axially chiral; conjugated polymers; electroluminescence ... See more keywords
Gold(I)‐catalyzed Synthesis of Axially Chiral Indolo[2,3‐c]carbazole Exhibiting Advanced Electrochromic Response
Sign Up to like & getrecommendations! Published in 2025 at "Asian Journal of Organic Chemistry"
DOI: 10.1002/ajoc.202400695
Abstract: The Wurster’s Blue skeleton embedded in an axially chiral indolo[2,3‐c]carbazole framework can act as a key chromophore to realize three‐way‐output electrochromic response (UV‐Vis‐near IR absorption, fluorescence, and circular dichroism) upon reversible electrochemical interconversion with the… read more here.
Keywords: indolo carbazole; axially chiral; chiral indolo; gold catalyzed ... See more keywords
Construction of Axially Chiral Biaryl Sulfonamides by Palladium/Chiral Norbornene Cooperative Catalysis
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DOI: 10.1002/cctc.202500560
Abstract: Aryl sulfonamide scaffold is a privileged pharmacophore, and is prevalent in pharmaceuticals. Existing aryl sulfonamide‐based pharmaceuticals are either achiral or limited to central chirality, leaving the potential of axially chiral biaryl sulfonamides underexplored. Beyond therapeutic… read more here.
Keywords: axially chiral; palladium chiral; chiral norbornene; biaryl sulfonamides ... See more keywords
Trigonostemons G and H, dinorditerpenoid dimers with axially chiral biaryl linkage from Trigonostemon chinensis.
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DOI: 10.1002/chir.23170
Abstract: Trigonostemons G and H, two novel dimeric dinorditerpenoids, were isolated from the stem barks of Trigonostemon chinensis. Their planar structures and relative configurations were established by extensive analysis of spectroscopic data. Trigonostemons G and H… read more here.
Keywords: biaryl; chiral biaryl; biaryl linkage; trigonostemon chinensis ... See more keywords
Axially chiral hemiaminals from nonracemic α-amino acid derivatives (thiohydantoins): Synthesis and isomer identification.
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DOI: 10.1002/chir.23274
Abstract: Stable, nonracemic axially chiral hemiaminals (O,N-hemiacetals) have been synthesized stereoselectively from lithium aluminum hydride (LiAlH4 ) reductions of nonracemic 5-methyl- and 5-isopropyl-3-(o-aryl)-2-thioydantoins in tetrahydrofuran (THF) at room temperature in 10 min. Predominantly S-configured hemiaminals at… read more here.
Keywords: nonracemic amino; amino acid; hemiaminals nonracemic; chiral hemiaminals ... See more keywords
Photophysical and Chiroptical Properties of Europium(III) Enantiomers with Axially Chiral Ancillary Ligands
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DOI: 10.1002/ejic.202500257
Abstract: Chiral lanthanide(III) complexes with superior circularly polarized luminescence (CPL) properties, especially for the efficient chiral europium(III) complexes with high dissymmetry factor (glum) obtained by rational design of coordination ligands, are important in the field of… read more here.
Keywords: axially chiral; ancillary ligands; europium iii; iii enantiomers ... See more keywords
Transition‐Metal‐Catalyzed Construction of Axially Chiral Carbonyl Compounds
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DOI: 10.1002/ejoc.202400995
Abstract: The synthesis of axially chiral carbonyl compounds has attracted considerable interest in organic synthesis due to their prevalence in natural products and pharmaceuticals, as well as their utility in material science and catalysis. Transition‐metal‐catalyzed approaches… read more here.
Keywords: metal catalyzed; transition metal; axially chiral; chiral carbonyl ... See more keywords
Copper‐Catalyzed Desymmetric Alkyne–Azide Cycloaddition to Access Axially Chiral Biaryls
Sign Up to like & getrecommendations! Published in 2025 at "European Journal of Organic Chemistry"
DOI: 10.1002/ejoc.202500041
Abstract: Axially chiral biaryls are an important class of structural units widely used in natural product synthesis, drug design, and as ligands for asymmetric catalysis. Although significant progress has been made in the synthesis of axially… read more here.
Keywords: axially chiral; chiral biaryls; alkyne; biaryls ... See more keywords
Green‐Tuning of (Chir)Optical Properties for Axially‐Chiral Boramidines
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DOI: 10.1002/hlca.202500059
Abstract: The integration of boron into π‐conjugated systems is a reliable approach to enhance photophysical properties. In this context, boramidines have emerged as a promising class of fluorophores. Herein, the design, synthesis, and chiroptical properties of… read more here.
Keywords: axially chiral; green tuning; chir optical; properties axially ... See more keywords
Development of Axially Chiral Urazole Scaffolds for Anti-plant Virus Applications against Potato Virus Y.
Sign Up to like & getrecommendations! Published in 2023 at "Pest management science"
DOI: 10.1002/ps.7428
Abstract: BACKGROUND Potato virus Y (PVY) was first discovered by Smith in 1931 and has currently been ranked as the fifth in the most significant plant viruses. It can cause severe damage to the plants from… read more here.
Keywords: development; potato virus; plant virus; axially chiral ... See more keywords
Atroposelective Synthesis of Axially Chiral Styrenes via an Asymmetric C–H Functionalization Strategy
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DOI: 10.1016/j.chempr.2019.12.011
Abstract: Summary Axially chiral styrenes, which exhibit a chiral axis between a substituted alkene and an aromatic ring, have been largely overlooked. The hurdle is the lower barriers to rotation compared with that of their biaryl… read more here.
Keywords: chiral styrenes; functionalization strategy; axially chiral; atroposelective synthesis ... See more keywords