Sliver-Catalyzed 1,3-Aza-Benzyl Migration of Allyl Alcohol.
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DOI: 10.1021/acs.orglett.2c02809
Abstract: Carbon migration of alkenyl alcohols has been recognized as an increasingly viable methodology in organic synthesis. Herein, we disclose a silver-catalyzed 1,3-aza-benzyl migration of allyl alcohols by utilizing chelation-assisted selective cleavage of an unstrained C(sp3)-C(sp3)… read more here.
Keywords: benzyl migration; sliver catalyzed; catalyzed aza; migration ... See more keywords