Synthesis of azadiphosphiridine complexes. Theoretical studies on ring formation, the P-to-P' metal shift and the resulting nitrogen geometry.
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DOI: 10.1039/d1dt04252a
Abstract: A set of azadiphosphiridine complexes 3a and 4b,c were synthesized in high selectivity using N-H and P-H deprotonation as key steps and RPCl2 as substrates (R = NiPr2 (a), -tBu (b), Ph (c)). While complex… read more here.
Keywords: theoretical studies; azadiphosphiridine complexes; geometry; ring formation ... See more keywords