Enantioselective Rh-Catalyzed Azide-Internal-Alkyne Cycloaddition for the Construction of Axially Chiral 1,2,3-Triazoles.
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DOI: 10.1021/jacs.2c01985
Abstract: Significant advances have been achieved for the construction of chiral skeletons containing 1,2,3-triazoles via transition-metal-catalyzed asymmetric azide-alkyne cycloaddition; however, most of them have been limited to terminal alkynes in the synthesis of central chirality via… read more here.
Keywords: azide internal; alkyne cycloaddition; catalyzed azide; axially chiral ... See more keywords