1,2-Diamination of Alkenes via 1,3-Dipolar Cycloaddition with Azidium Ions or Azides.
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DOI: 10.1021/acs.orglett.2c03908
Abstract: We describe two new methods for the 1,2-diamination of alkenes. First, either an azidium ion (ArN═N+═NAr) undergoes 1,3-dipolar cycloaddition with an alkene to give a 1,2,3-triazolinium ion directly, or an intramolecular azide-alkene cycloaddition followed by… read more here.
Keywords: dipolar cycloaddition; azidium; via dipolar; diamination alkenes ... See more keywords