Crystal structure and magnetic interactions of a new alkoxido and azido bridged 1D copper(II) coordination polymer
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Solid State Chemistry"
DOI: 10.1016/j.jssc.2021.122484
Abstract: Abstract A new 1D azido and alkoxido-bridged Cu(II) coordination polymer, [Cu2(H3L)(μ-H2L)(μ-N3)]n (1), was synthesized from the reaction of H4L, Cu(NO3)2·3H2O and NaN3 in methanol, where H4L is (E)-2-((5-bromo-2-hydroxybenzylidene)amino)-2-(hydroxymethyl)propane-1,3-diol. Compound 1 was characterized by elemental analysis,… read more here.
Keywords: copper; coordination; azido; crystal structure ... See more keywords
Azido-Functionalized Aromatic Phosphonate Esters in RPOSS-Cage-Supported Lanthanide Ion (Ln = La, Nd, Dy, Er) Coordination.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c00266
Abstract: Within this work, a modified preparation of diethyl 4-azidobenzylphosphonate (L1) is presented and the family of 4- or 4'-azido-substituted aromatic phosphonate esters is increased by three new ligand platforms: diisopropyl 4-azidobenzylphosphonate (L2), diisopropyl ((4'-azido-[1,1'-biphenyl]-4-yl)methyl)phosphonate (L3),… read more here.
Keywords: aromatic phosphonate; phosphonate esters; cage supported; azido ... See more keywords
An Azido-Cyanide Mixed-Bridged [Fe4Ni4] Single-Molecule Magnet.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b03559
Abstract: Taking advantages of both azide and cyanide bridges in magnetism and synthesis, an azido-cyanide mixed-bridged octanuclear [FeIII4NiII4] SMM of [{(enbzpy)Ni2(μ1,1-N3)2·(DMF)}{Tp*Fe(CN)3}2]2·2DMF·14H2O (1) was explored and characterized, which exhibits slow relaxation of the magnetization and an S… read more here.
Keywords: cyanide mixed; mixed bridged; azido; bridged fe4ni4 ... See more keywords
Zinc(ii)-mediated stereoselective construction of 1,2-cis 2-azido-2-deoxy glycosidic linkage: assembly of Acinetobacter baumannii K48 capsular pentasaccharide derivative
Sign Up to like & getrecommendations! Published in 2024 at "Chemical Science"
DOI: 10.1039/d4sc03449j
Abstract: The capsular polysaccharide (CPS) is a major virulence factor of the pathogenic Acinetobacter baumannii and a promising target for vaccine development. However, the synthesis of the 1,2-cis-2-amino-2-deoxyglycoside core of CPS remains challenging to date. Here… read more here.
Keywords: acinetobacter baumannii; baumannii k48; azido deoxy; azido ... See more keywords
Azido-enabled thermal history analysis on a metal-oxide surface.
Sign Up to like & getrecommendations! Published in 2025 at "Nanoscale"
DOI: 10.1039/d5nr01176k
Abstract: A novel strategy for localized thermal history analysis using organic azides immobilized on ZnO nanowire arrays is presented. The pyrolysis of the surface azido groups followed by the introduction of molecular probes to the residual… read more here.
Keywords: history; thermal history; analysis; history analysis ... See more keywords
Concomitant dimorphism in poly[di-μ-azido-(5,5'-dimethyl-2,2'-bipyridine)iron(II)].
Sign Up to like & getrecommendations! Published in 2022 at "Acta crystallographica. Section C, Structural chemistry"
DOI: 10.1107/s2053229622006908
Abstract: The title metal-organic polymer, catena-poly[[(5,5'-dimethyl-2,2'-bipyridine-κ2N,N')iron(II)]-di-μ-azido-κ2N1:N3-[(5,5'-dimethyl-2,2'-bipyridine-κ2N,N')iron(II)]-di-μ-azido-κ2N1:N1], [Fe(N3)2(C12H12N2)]n, features alternating μ-1,1 (end-on mode of coordination) and μ-1,3 (end-to-end mode of coordination) double azide bridges, forming chains running in the [100] direction. The octahedral coordination geometry around the… read more here.
Keywords: dimethyl bipyridine; azido; bipyridine iron;
Molecular, Supramolecular Structures Combined with Hirshfeld and DFT Studies of Centrosymmetric M(II)-azido {M=Ni(II), Fe(II) or Zn(II)} Complexes of 4-Benzoylpyridine
Sign Up to like & getrecommendations! Published in 2021 at "Symmetry"
DOI: 10.3390/sym13112026
Abstract: The supramolecular structures of the three metal (II) azido complexes [Fe(4bzpy)4(N3)2]; 1, [Ni(4bzpy)4(N3)2]; 2 and [Zn(4bzpy)2(N3)2]n; 3 with 4-benzoylpyridine (4bzpy) were presented. All complexes contain hexa-coordinated divalent metal ions with a slightly distorted octahedral MN6… read more here.
Keywords: azido; molecular supramolecular; azido complexes; combined hirshfeld ... See more keywords