End-to-End Azido-Bridged Lanthanide Chain Complexes (Dy, Er, Gd, and Y) with a Pentadentate Schiff-Base [N3O2] Ligand: Synthesis, Structure, and Magnetism.
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DOI: 10.1021/acs.inorgchem.9b02825
Abstract: The syntheses, structure and magnetic properties are reported for five novel 1D polymeric azido-bridged lanthanide complexes with the general formula {[Ln(DAPMBH)(N3)C2H5OH]C2H5OH}n where H2DAPMBH = 2,6-diacetylpyridine bis(4-methoxybenzoylhydrazone)-a new pentadentate pyridine-base [N3O2] ligand and Ln = Dy… read more here.
Keywords: chain; end; azido bridged; structure ... See more keywords
Two azido-bridged homospin Fe(ii)/Co(ii) coordination polymers featuring single-chain magnet behavior.
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DOI: 10.1039/d0dt00181c
Abstract: Two azido-bridged homospin Fe(ii)/Co(ii) coordination polymers [Fe2(Bzp)2(N3)4]n (1) and [Co4(Bzp)4(N3)8·(MeOH)2]n (2) (bzp = 2-benzoylpyridine) are prepared, which consist of one-dimensional neutral chains with pure EO-azido (μ2-1,1-N3) bridges. Magnetically, both 1 and 2 exhibit considerable intrachain… read more here.
Keywords: chain; bridged homospin; homospin coordination; azido bridged ... See more keywords
A rare example of a double metamagnetic transition leading to 2D and 3D long-range order in the two-dimensional pyrazine- and azido-bridged cobalt(II) compound [Co(pyz)(N3)2].
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DOI: 10.1039/d2dt00294a
Abstract: The synthesis, characterization, crystal structure and detailed magnetic properties of a pyrazine (pyz) and azido (N3) bridged cobalt(II) compound of formula [Co(N3)2(pyz)] (1) are reported. Compound 1 shows a layered structure formed by Co(II) chains… read more here.
Keywords: compound; azido bridged; long range; bridged cobalt ... See more keywords